Humidity properties of Schiff base polymers
نویسندگان
چکیده
منابع مشابه
Photoreduction of bacteriorhodopsin Schiff base at low humidity. A study with C13=C14 nonisomerizable artificial pigments.
The retinal protonated Schiff base of bacteriorhodopsin is photoreactive to reducing agents such as NaBH4. In the present work we have studied the effect of different protein hydration levels on the photoreductive reaction, as well as the consequences of preventing isomerization around the critical C13=C14 retinal double bond. It was revealed that the rate of light-induced NaBH4 reaction can be...
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Normal and sickle erythrocytes were exposed in vitro to millimolar concentrations of 31 different carbonyl compounds. Schiff base (imine) linkages were formed with amino groups of intracellular hemoglobin. Adducts were isolated by gel electrofocusing and could be dissociated by dialysis. Aromatic aldehydes proved more reactive than aliphatic aldehydes, and ketones were unreactive. The influence...
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Three new lanthanide 1-D coordination polymers ({[Ln(2)(H(2)L)(OAc)(6)]·EtOH·2H(2)O}(n) (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc)(2)(H(2)O)}(n) (3)) and a heterobinuclear complex [YbNiLCl(3)(H(2)O)(3)] (4) are reported which are formed from salen type Schiff-base ligands H(2)L (H(2)L = N,N'-bis(3-methoxysalicylidene)butane-1,4-diamine). The polymeric structures are formed by bridging H(2)L units ...
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Mobile carrier properties of two schiff base ligands, named <span style="font-size: 10.0pt; font-family: 'Times New Roman','serif'; mso-fareast-font-family: 'Times New Roman'; mso-ansi-langua...
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An imine-based 2D polymer side-functionalized with o-hydroxyl group was designed in regard to its potential ability to serve as a chelating agent and synthesized on a highly oriented pyrolytic graphite surface with a relatively low annealing temperature. When annealed to a higher temperature the o-hydroxyl group reacts further with the imine group, leading to the formation of oxazoline, which c...
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ژورنال
عنوان ژورنال: Open Chemistry
سال: 2018
ISSN: 2391-5420
DOI: 10.1515/chem-2018-0106